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Circular Raman responses from angular-momentum inequivalence in CoSi

arXiv:2606.06909v1 Announce Type: new Abstract: Circularly polarized Raman scattering in solids exhibits distinct phenomena such as Raman optical activity (ROA) and chiral-phonon-induced frequency splitting, whose relationship has remained unclear. Here we show that these seemingly different responses can be understood within a common framework based on the inequivalence of phonon states carrying opposite crystal angular momenta. Using helicity-resolved Raman spectroscopy of the chiral...

arXiv Physics 2d ago

Achiral crystal reveals Raman optical activity through ferroaxial order

Raman optical activity, long thought to require chiral molecules or magnetic order, has been demonstrated in an achiral, nonmagnetic crystal by researchers at the Institute of Science Tokyo. The effect arises through ferroaxial order, a coordinated rotation of atoms within the lattice, and is detected using circularly polarized Raman spectroscopy. The findings show that optically inactive materials can also display chirality-like optical responses and expand the scope of optical techniques...

Phys.org 2d ago