Br{\o}nsted-Evans-Polanyi
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Related Articles from SNS
On the Covalent Fields of Molecule-Surface Interactions
arXiv:2606.08619v1 Announce Type: new Abstract: The ambiguity of the active site, the empirical status of Br{\o}nsted-Evans-Polanyi relations, and the unpredictability of linear scaling relation breakdown are three symptoms of a single representational choice: treating chemical affinity as an attribute of discrete geometric sites. Here we show that all three are resolved when chemical affinity is represented as a continuous property of the interface: the covalent field. We present a...