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Electron Paramagnetic Resonance

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Electron Paramagnetic Resonance Study of Radical Species on NaNbO3@CeO2-Modified Carbon Vulcan XC72 Gas Diffusion Electrode for Electrochemical Degradation of Paracetamol via Electro-Fenton

Announce Type: new Abstract: While electrochemical oxidation is a promising technology for water treatment, a fundamental understanding of the specific radical mechanisms involved in pharmaceutical degradation has remained limited. This study addresses this gap by employing Electron Paramagnetic Resonance (EPR) spectroscopy to directly quantify the radical species generated during the degradation of paracetamol using a novel gas diffusion electrode (GDE) modified with NaNbO3 nanocubes and...

arXiv Physics 11h ago

\emph{Ab initio} derivation of the crystal field parameters for lanthanide ions: The f$^1$ case

arXiv:2511.18837v2 Announce Type: replace Abstract: The crystal field theory as explained by Abragam and Bleaney in their landmark 1970 book on transition-ion electron paramagnetic resonance remains a cornerstone in the development of luminescence applications and molecular magnets based on the $f$-elements. The modern numerical derivation of the 27 $B_k^q$ Stevens crystal field parameters (CFPs), which describe the splitting of the energy levels of a central ion, is traditionally achieved...

arXiv Physics 6d ago