Husimi

A Phase Space Signature of Quantum Roaming in Chesnavich's Model

Announce Type: new Abstract: Roaming reactions occur when a molecule enters a near-dissociation region, avoids immediate separation, and later forms products by a pathway not controlled by the conventional tight transition-state bottleneck. Classical studies have shown that roaming is best understood in phase space: inner and outer transition-state structures, together with their invariant manifolds, organize trapping, return, and dissociation. The corresponding quantum question is less settled.