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Model for Hydrogen-Bond-Induced Dissociation of HF

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Static Electric Fields as a Model for Hydrogen-Bond-Induced Dissociation of HF and HCl

arXiv:2606.09011v1 Announce Type: new Abstract: The influence of static electric fields on the electronic structure and dissociation behavior of the polar diatomics \ce{HF} and \ce{HCl} is investigated using quantum chemical calculations. Ground- and excited-state potential energy surfaces (PESs) are computed as a function of bond distance and external electric field strength to examine field-induced modifications of chemical bonding. The calculations reveal pronounced bond softening and...

arXiv Physics 1d ago