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Polymer-Regulated Freezing of Water Droplets Revealed by Synchrotron X-ray Imaging and Raman Spectroscopy

arXiv:2606.01251v1 Announce Type: cross Abstract: Adding a polymer to a sessile water droplet not only lowers its freezing point but also suppresses the tip singularity that forms during its freezing on cold substrates. Here, we employ synchrotron X-ray and Raman imaging to elucidate the spatiotemporal mechanism underlying tip suppression in an aqueous polyvinyl alcohol (PVA) solution, a model polymer solution. As the polymer concentration increases, we observe slower propagation of the...

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