the Electric-Dipole Approximation
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Related Articles from SNS
Generalized Einstein Relations between Absorption and Emission Spectra in the Electric-Dipole Approximation
arXiv:2603.10416v2 Announce Type: replace Abstract: Recently, Ryu et al. showed that two broadened bands connected by a set of four Einstein-coefficient spectra for stimulated and spontaneous single-photon transitions will obey detailed balance at equilibrium if the spectra satisfy generalized Einstein relations. Here, quantum mechanical expressions for Einstein-coefficient spectra are obtained in the electric-dipole approximation using an intramolecular Boltzmann distribution and the...