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Onsager's Real Cavity model near solid interfaces
arXiv:2512.19714v2 Announce Type: replace-cross Abstract: We develop an extended Onsager real-cavity framework to describe the Casimir--Polder interaction of small molecules dissolved in dielectric liquids near planar interfaces. By analytically resolving the geometry of the cavity opening, we derive closed-form expressions that capture the modification of the interaction as the molecule approaches a surface and connect smoothly to the asymptotic medium-assisted limit. Using experimentally...